冀中坳陷东北部石炭-二叠系烃源岩热史及成熟史模拟          下载免费PDF全文

张松航  梁宏斌  唐书恒  钱铮  赵俊斌 《高校地质学报》2014,20(3):454

石炭-二叠系煤成气藏是冀中坳陷东北部亟待突破的勘探领域。文中基于大量的钻井、测井、地球化学和古地温资
料,分别模拟构建了大城凸起、文安斜坡和武清凹陷的埋藏史和考虑岩浆热液侵入作用的热演化史。研究结果表明冀中坳
陷东北部石炭-二叠系地层总体上经历了“三沉两抬”的构造演化过程,在印支运动前全区具有近似的演化历史,印支
期、燕山期区内构造演化开始分异,至新生代形成总体“东隆西坳”的构造格局。区内烃源岩热演化包括一次生烃和二次
生烃,并可细分为长期隆升型、后期强烈沉降深成变质型和岩浆热变质型三种类型。一次成烃主要发生在三叠系末期,二
次成烃分别在新近纪和古近纪岩浆侵入期。区内斜坡浅部和隆起区一次成烃,斜坡和凹陷深部为后期强烈沉降深成变质二
次成烃、斜坡和凸起岩浆热液侵入区发生岩浆热变质二次成烃。一次成烃期Ro 值在0.7%左右,不具成藏潜力,二次成烃
期烃源岩可达高熟、过熟阶段,成藏配置条件好,成藏潜力巨大。  相似文献   

鄂尔多斯盆地西南缘奥陶系马家沟组烃源岩饱和烃特征研究   总被引：1，自引：0，他引：1  

高占冬  张中宁  郑建京 《矿物岩石地球化学通报》2014,33(6)

奥陶系马家沟组是鄂尔多斯盆地下古生界的烃源岩层系之一,为了进一步认识马家沟组烃源岩的地球化学特征,本文以鄂尔多斯盆地西南缘典型剖面烃源岩样品为研究对象,利用GC-MS分析方法对研究样品的饱和烃馏分进行了分析。研究表明鄂尔多斯盆地西南缘马家沟组烃源岩岩性不同,其生物标志化合物分布特征也存在差异。根据生物标志化合物特征推断,马家沟组各类源岩的沉积环境为盐度较高的还原环境,灰岩沉积环境的氧化性略高于灰质泥岩;灰岩的有机质母质来源以低等水生生物和微生物为主,而灰质泥岩有高等植物来源的有机质混入,有机质的热演化程度均达到成熟阶段;马家沟组各类源岩有机质均经历过降解作用,且碳质泥岩中有机质遭受的降解作用要强于灰岩。  相似文献   

山东烟台大季家地区海水入侵界面划分的意义     

宋希利  ;宋鹏  ;时彦芳  ;耿祥峰 《山东地质》2014,(6):58-61

在沿海地区划分海水入侵界线具有重大意义,在海水入侵范围内,地下水由于含盐量高,虽然工业生产、人畜生活不能利（饮）用,但深部海水可为海产品养殖业带来较高的利用价值。利用高密度电法和可控源音频大地电磁2种方法准确划分了浅、深部海水入侵界线,并根据电性特征分析探讨了海水入侵区域的由浅至深的侵入特点,推测了不同深度上岩石破碎及富水规律,为探讨沿海养殖业利用温度相对稳定或较高的深部入侵海水进行了积极、有益的探讨。  相似文献   

可控源法在海阳市郭城地区鑫泰金矿床成矿规律中的应用     

郭国强  郭朋  张超  何玉海  于义文  陈大磊 《山东地质》2014,(6):74-76

可控源音频大地电磁法（CSAM T法）是一种利用人工场源研究地层、构造等深部地质特征问题的新技术新方法。在山东省海阳市郭城地区鑫泰金矿床的应用研究表明,CSAM T 法可以较好地用于确定矿体的产状和大致地层结构,在矿体成矿规律研究方面具有较为突出的应用效果。  相似文献   

重庆洪官渡铝土矿床镓元素地球化学特征及其成矿环境探讨          下载免费PDF全文

孙洁  赵晓东  李军敏  陈莉  吕涛  陈阳  贾德龙 《沉积与特提斯地质》2014,34(3):106-112

重庆洪官渡铝土矿床伴生Ga含量普遍超过了工业综合利用指标。Ga与Cr、TiO2呈强正相关,与V呈中等程度的正相关,与Al2O3、Fe2O3不相关。根据Sr/Ba、u/Th、Ga/Al等地球化学指标值特征,判断该铝土矿床的含矿岩系属海陆交互沉积,但以陆相沉积为主;同时,洪官渡铝土矿床是在以淡水作用为主的弱酸性氧化环境的中形成。  相似文献   

南秦岭造山型金矿地质特征及成矿模式——以陕西山阳夏家店金(钒)矿床为例     

任涛  王瑞廷  孟德明  樊忠平  李剑斌  王向阳 《西北地质》2014,(1):150-158

在总结山阳夏家店金(钒)矿床产出地质背景、矿床地质特征的基础上,分析和研究了矿区控矿因素、成矿元素基本分布统计规律、成矿流体特征、同位素特征,建立了矿床成矿模式。该矿床金矿体主要受含矿岩系和镇安-板岩镇断裂的次级断裂控制,从地表到深部金的品位、厚度呈波状变化,走向上呈尖灭再现趋势,流体包裹体主要为气液两相,以富CO2(10%)、低盐度(3%~5%)为特征,主成矿期均一温度集中于240~280℃,成矿深度为3km。同位素分析显示成矿流体主要来源于大气水与建造水的混合,部分来源于深部。由此建立了夏家店金矿成矿模式,认为夏家店金矿床以构造-流体成矿作用为主,是由构造的多期作用形成薄弱带,地下热卤水经地热或岩浆驱动在构造薄弱带附近循环萃取矿源层中的矿质在构造带中沉淀而形成的造山型金矿。  相似文献   

河南新安县郁山铝土矿床地质特征、成矿规律及成矿物质来源     

焦赞超  梁会娟  刘传权  刘百顺  李中明  霍清华  王庆飞  乔玉兰 《西北地质》2014,(1):221-233

河南郁山铝土矿区包括郁山、李村、杏树洼、煤窑洼4个铝土矿段。本溪组含铝岩系的分布、埋深及岩相特征直接控制铝土矿的赋存和空间特征。区内构造对含矿岩系的分布、产状、埋深及完整性等有重要的控制作用。含铝岩系厚度与铝土矿厚度及品位一般呈正变关系,即含铝岩系厚度大,铝土矿层厚而富。铝土矿物沉积于古地形中,大的凹陷沉积盆地控制着铝土矿带的分布范围和展布方向,其中小的洼地、溶洞、溶斗等具体控制铝土矿的矿体形态、产状、规模。河南郁山铝土矿为典型的喀斯特型铝土矿。铝土矿成矿物质均来自上地壳,为上地壳岩石经过风化而成,非花岗岩以及玄武岩等岩石类型;铝土矿物质来源与基底碳酸盐岩关系不大,具有一定距离的搬运,说明铝土矿物质来源非原地,而是异地来源;秦岭古陆提供了重要成矿物质。  相似文献   

Metallogenic and Metamorphic Age of the Hongtoushan Copper–Zinc Massive Sulfide Deposit,Liaoning Province,China     

Ye Qian  Fengyue Sun  Yajin Zhang  Liang Huo 《Resource Geology》2014,64(1):17-24

The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U^?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U^?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.  相似文献   

Geochronology and geochemistry of Cretaceous Nanshanping alkaline rocks from the Zijinshan district in Fujian Province,South China: Implications for crust–mantle interaction and lithospheric extension     

《Journal of Asian Earth Sciences》2014

In situ zircon U–Pb ages and Hf isotopic data, major and trace elements, and Sr–Nd–Pb isotopic compositions are reported for Nanshanping alkaline rocks from the Zijingshan district in southwestern Fujian Province (the Interior or Western Cathaysia Block) of South China. The Nanshanping alkaline rocks, which consist of porphyritic quartz monzonite, porphyritic syenite, and syenite, revealed a Late Cretaceous age of 100–93 Ma. All of the rocks show high SiO₂, K₂O + Na₂O, and LREE but low CaO, Fe₂O₃^T, MgO, and HFSE (Nb, Ta, P, and Ti) concentrations. These rocks also exhibit uniform initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7078 to 0.7087 and ε_Nd(t) values of −4.1 to −7.2, thus falling within the compositional field of Cretaceous basalts and mafic dikes occurring in the Cathaysia Block. Additionally, these rocks display initial Pb isotopic compositions with a ²⁰⁶Pb/²⁰⁴Pb_i ratio of 18.25 to 18.45, a ²⁰⁷Pb/²⁰⁴Pb_i ratio of 15.63 to 15.67, and a ²⁰⁸Pb/²⁰⁴Pb_i ratio of 38.45 to 38.88. Combined with the zircon Hf isotopic compositions (ε_Hf(t) = −11.7 to −3.2), which are different from those of the basement rocks, we suggest that Nanshanping alkaline rocks were primarily derived from a subduction-related enriched mantle source. High Rb/Sr (0.29–0.65) and Zr/Hf (37.5–49.2) but relatively low Ba/Rb (4.4–8.1) ratios suggest that the parental magmas of these rocks were most likely formed via partial melting of a phlogopite-bearing mantle source with carbonate metasomatism. The relatively high SiO₂ (62.35–70.79 wt.%) and low Nb/Ta (10.0–15.3) ratios, positive correlation between SiO₂ and (⁸⁷Sr/⁸⁶Sr)_I, and negative correlation between SiO₂ and ε_Nd(t) of these rocks suggest that the crustal materials were also involved in formation of the Nanshanping alkaline rocks. Combined with geochemical and isotopic features, we infer magmatic processes similar to AFC (assimilation and fractional crystallization) involving early fractionation of clinopyroxene and olivine and subsequent fractionation of biotite-dominated assemblages coupled with a lesser amount of crustal contamination, thereby forming the Nanshanping alkaline rocks. The Nanshanping alkaline rocks appear to be associated with an extensional environment in the Cathaysia Block. This extensional regime could have resulted in the slab break-off and rollback of the subducting paleo-Pacific plate and the upwelling of the asthenospheric mantle, which induced partial melting of the enriched lithospheric mantle in the Cretaceous.  相似文献   

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry     

Monica E. Erdman  Cin‐Ty A. Lee  Wenbo Yang  Lynn Ingram 《Geostandards and Geoanalytical Research》2014,38(1):51-60

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.  相似文献